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Chemical composition of common copper alloys and comparison of domestic and foreign brands

Release time:2020-07-28Click:2953

Chemical constituents commonly used in Chinese bronze medallion

1、 Lead brass series

牌号主要身分杂质身分    %杂质总和 %
CuPbZnFeNi
HPb59-157-600.8-1.9余量≤0.5≤1.0≤1.0
HPb59-257.5-59.52.0-2.8余量≤0.5--≤1.2
HPb59-357.5-59.52.0-3.0余量≤0.5≤0.5≤1.2
HPb60-258-611.5-2.5余量≤0.3--
HPb62-260-631.5-2.5余量≤0.15--
HPb62-360-632.5-3.7余量≤0.35--
HPb63-362-652.4-3.0余量≤0.1≤0.5≤0.75

2、 Ordinary brass series

主身分杂质身分    %杂质总和 %
CuZnPbFeNi
H5957-60余量≤0.5≤0.3≤0.5≤1.0
HP6257-60余量≤0.08≤0.15≤0.5≤0.5
H6563.5-68余量≤0.03≤0.1≤0.5≤0.3
H6867-70余量≤0.03≤0.1≤0.5≤0.3
H7068.5-71.5余量≤0.03≤0.1≤0.5≤0.3
H8079-81余量≤0.03≤0.1≤0.5≤0.3
H8584-86余量≤0.03≤0.1≤0.5≤0.3
H9088-91余量≤0.03≤0.1≤0.5≤0.2
H9695-97余量≤0.03≤0.1≤0.5≤0.2

3、 Copper series

名称代号Cu+AgPAgBiSbAsFeNiPbSnSZnO
一号铜T199.950.001-0.0010.0020.0020.0050.0020.0030.0020.0050.0050.02
二号铜T299.9--0.0010.0020.0020.005-0.005-0.005--
三号铜T399.7--0.002----0.01----
零号 无氧铜TU099.990.000300.00010.00040.00050.0010.0010.00050.00020.00150.00010.0005
Se:0.001;Te:0.001;Cd:0.0001
一号 无氧铜TU199.970.002-0.0010.0020.0020.0040.0020. 0030.0020.0040.0030.002
二号 无氧铜TU299.950.002-0.0010.0020.0020.0040.0020.0040.0020.0040.0030.003
一号磷脱氧铜TP199.90.004-0.012-----------
二号磷脱氧铜TP299.90.015-0.020-----------

Chemical composition of commonly used Japanese grade copper alloys

1、 Lead brass series

牌号主要身分杂质身分    %杂质总和 %对应中国牌号
CuPbZnFeSn
C360159.0-63.01.8-3.7余量≤0.3Fe+Sn≤0.5≤1.0HPb62-3
C360259.0-63.01.8-3.7余量≤0.5Fe+Sn≤1.2≤1.2HPb60-2
C360357.0-61.01.8-3.7余量≤0.35Fe+Sn≤0.6≤1.2HPb60-2
C360457.0-61.01.8-3.7余量≤0.5Fe+Sn≤1.2-HPb59-3
C3605 56.0-60.03.5-4.5余量≤0.5Fe+Sn≤1.2-HPb59-3
C377157.0-61.01.0-2.5余量Fe+Sn≤1.0-HPb59-1

2、 Ordinary brass series

牌号主身分杂质身分    %杂质总和 %对应中国牌号
CuZnPbFeNi
C280059-62余量≤0.07≤0.1----H59
C272062-64余量≤0.07≤0.07----HP62
C270063-67余量≤0.05≤0.05----H65
C268064-68余量≤0.05≤0.05Bi≤0.002Sb≤0.005H68
C260068.5-71.5余量≤0.05≤0.05----H70
C240078.5-81.5余量≤0.05≤0.05----H80
C230084-86余量≤0.05≤0.05----H85
C220089-91余量≤0.05≤0.05----H90
C210094-96余量≤0.05≤0.05----H96

3、 Copper series

牌号化学身分,%对应中国牌号
Cu+AgPAgBiSbAsFeNiPbSnSZnO
C102099.96------------T1
C110099.9------------T2
C122199.750.004-0.04-----------T3
C101199.990.0003-0----0-000TU0
Hg:0.0001;Se:0.001;Te:0.001;Cd:0.0001
C102099.96------------TU1、TU2
C120199.90.004-0.015-----------TP1
C122099.90.015-0.040-----------TP2

Chemical composition of commonly used German grade copper alloy

1、 Lead brass series

牌号代号主要身分杂质身分    %杂质总和对应中国牌号
CuPbZnFeAlNiSn%
CuZn36Pb3--60-622.5-3.5余量≤0.3≤0.05≤0.3≤0.2≤0.2HPb62-3
CuZn39Pb2CW612N58.5-601.5-2.5余量≤0.4--≤0.3≤0.2≤0.2HPb60-2
CuZn39Pb3CW614N57-592.5-3.5余量≤0.5≤0.1≤0.5≤0.4≤0.2HPb59-3
CuZn40Pb2CW617N57-591.5-2.5余量≤0.4≤0.1≤0.4≤0.3≤0.2HPb59-1

2、 Ordinary brass series

牌号主身分杂质身分    %杂质总和 %对应中国牌号
CuZnPbFeAlSnNi
CuZn40 2.036059.5-61余量≤0.3≤0.2≤0.05≤0.2≤0.3≤0.2H59
CuZn37 2.032162-64余量≤0.1≤0.1≤0.03≤0.1≤0.3≤0.1HP62
CuZn33 2.028066-68.5余量≤0.05----≤0.05--≤0.1H65
CuZn30 2.026569-71余量≤0.05----≤0.05--≤0.1H68、H70
CuZn20 2.025078.5-81.5余量≤0.05≤0.05≤0.02≤0.05≤0.2≤0.1H80
CuZn15 2.024084-86余量≤0.05≤0.05≤0.02≤0.05≤0.2≤0.1H85
CuZn10 2.023089-91余量≤0.05≤0.05≤0.02≤0.05≤0.2≤0.1H90
CuZn5 2.022094-96余量≤0.05≤0.05≤0.02≤0.05≤0.2≤0.1H96

3、 Copper series

牌号化学身分,%对应
Cu+AgPAgBiSbAsFeNiPbSnSZnO中国牌号
OF-Cu .004099.95------------T1、TU1
SE-Cu2.007099.90.003-----------T2
SW-Cu2.007699.90.005-0.014-----------TP1
SW-Cu2.007699.90.015-0.040-----------TP2

Comparison table of copper alloy grades

1、 Lead brass number comparison table

中国牌号 日本牌号 德国牌号 美国牌号英国牌号
HPb59-1C3710CuZn40Pb2C37000CZ120
HPb59-3 C3561CuZn40Pb3 C37710CZ121Pb3
HPb60-2 C3771CuZn39Pb2C37700CZ120
HPb62-2 C3713CuZn38Pb2C35300CZ119
HPb62-3 C3601CuZn36Pb3C36000CZ124
HPb63-3 C3560 CuZn36Pb3C35600CZ124

2、 Comparison table of common brass grades

中国牌号 日本牌号 德国牌号 美国牌号英国牌号
H59 C2800 CuZn40 C28000 CZ109 
H62C2720 CuZn40 C27400 CZ109 
H65C2680 CuZn35 C27000 CZ107
H68C2600 CuZn30 C26000 CZ106
H70C2600 CuZn30 C26000 CZ106
H80C2400 CuZn20 C24000 CZ103
H85C2300 CuZn15 C23000 CZ102
H90C2200 CuZn10 C22000 CZ101
H96 C2100 CuZn5 C21000 --

3、 Comparison table of copper grades

名 称 中国牌号 日本牌号 德国牌号 美国牌号 英国 
零号无氧铜 TU0 C1011 --C10100 C110 
一号无氧铜 TU1C1020OF-Cu C10200 C103 
二号无氧铜 TU2C1020OF-Cu C10200 C103 
一号铜 T1 C1020OF-Cu C10200 C103 
二号铜 T2C1100 SE-Cu C11000 C101 
三号铜 T3C1221 ------
一号磷脱氧铜 TP1 C1201 SW-Cu C12000 --
二号磷脱氧铜 TP2C1220 SF-Cu C12000 --

Chemical composition of common copper alloy grades -- German grade

1、 Lead brass series

牌号代号主要身分杂质身分    %杂质总和对应中国牌号
CuPbZnFeAlNiSn%
CuZn36Pb3--60-622.5-3.5余量≤0.3≤0.05≤0.3≤0.2≤0.2HPb62-3
CuZn39Pb2CW612N58.5-601.5-2.5余量≤0.4--≤0.3≤0.2≤0.2HPb60-2
CuZn39Pb3CW614N57-592.5-3.5余量≤0.5≤0.1≤0.5≤0.4≤0.2HPb59-3
CuZn40Pb2CW617N57-591.5-2.5余量≤0.4≤0.1≤0.4≤0.3≤0.2HPb59-1

2、 Ordinary brass series

牌号主身分杂质身分    %杂质总和 %对应中国牌号
CuZnPbFeAlSnNi
CuZn40 2.036059.5-61余量≤0.3≤0.2≤0.05≤0.2≤0.3≤0.2H59
CuZn37 2.032162-64余量≤0.1≤0.1≤0.03≤0.1≤0.3≤0.1HP62
CuZn33 2.028066-68.5余量≤0.05----≤0.05--≤0.1H65
CuZn30 2.026569-71余量≤0.05----≤0.05--≤0.1H68、H70
CuZn20 2.025078.5-81.5余量≤0.05≤0.05≤0.02≤0.05≤0.2≤0.1H80
CuZn15 2.024084-86余量≤0.05≤0.05≤0.02≤0.05≤0.2≤0.1H85
CuZn10 2.023089-91余量≤0.05≤0.05≤0.02≤0.05≤0.2≤0.1H90
CuZn5 2.022094-96余量≤0.05≤0.05≤0.02≤0.05≤0.2≤0.1H96

3、 Copper series

牌号化学身分,%对应
Cu+AgPAgBiSbAsFeNiPbSnSZnO中国牌号
OF-Cu .004099.95------------T1、TU1
SE-Cu2.007099.90.003-----------T2
SW-Cu2.007699.90.005-0.014-----------TP1
SW-Cu2.007699.90.015-0.040-----------TP2

Chemical composition of common American copper alloy grades

1、 Lead brass series

牌号主要身分杂质身分 %杂质总和 %对应中国牌号
CuPbZnFeSn
C3530060-631.5-2.5余量≤0.15----HPb62-2
C3600060-632.5-3.7余量≤0.35----HPb62-3
C3770058-611.5-2.5余量≤0.30----HPb60-2
C3850055-602.0-3.8余量≤0.35----HPb59-3

2、 Ordinary brass series

牌号主身分杂质身分    %杂质总和 %对应中国牌号
CuZnPbFeNi
C2800059-63余量≤0.3≤0.07----H59
C2740061-64余量≤0.10≤0.05----HP62
C2700063-68.5余量≤0.10≤0.07----H65
C2600068.5-71.5余量≤0.07≤0.05----H68、H70
C2400078.5-81.5余量≤0.05≤0.05----H80
C2300084-86余量≤0.05≤0.05----H85
C2200089-91余量≤0.05≤0.05----H90
C2100094-96余量≤0.03≤0.05----H96

3、 Copper series

牌号化学身分,%对应中国牌号
Cu+AgPAgBiSbAsFeNiPbSnSZnO
C1020099.95-----------0T1
C1100099.9------------T2
C1010099.993E-040000005E-040000TU0
Hg:0.0001,Se:0。0003,Te:0.0002,Mn:0.00005,Cd:0.0001
C1020099.95-----------0TU1、TU2
C1200099.90.004-0.012-----------TP1
C1220099.90.015-0.040-----------TP2

Chemical composition of common copper alloy grades -- British grade

1、 Lead brass series

牌号主要身分杂质身分 %杂质总和 %对应中国牌号
CuPbZnFeSn
CZ12058-601.5-2.5余量----≤0.3HPb59-1、 HPb60-2
CZ121Pb356.5-58.52.5-3.5余量≤0.3--≤0.7HPb59-3
CZ11961-641.0-2.5余量----≤0.3HPb62-2
CZ12460-632.5-3.7余量≤0.3--≤0.5(除铁外)HPb62-3、 HPb63-3

2、 Ordinary brass series

牌号主身分杂质身分    %杂质总和 %对应中国牌号
CuZnPbFeNi
CZ10959-62余量≤0.1----0.3(除Pb外)H59、HP62
CZ10764-67余量≤0.1≤0.1--0.4H65
CZ10668.5-71.5余量≤0.05≤0.05--0.3H68、H70
CZ10379-81余量≤0.05≤0.1--0.4H80
CZ10284-86余量≤0.05≤0.1--0.4H85
CZ10189-91余量≤0.05≤0.1--0.4H90

3、 Copper series

牌号化学身分,%对应中国牌号
Cu+AgPAgBiSbAsFeNiPbSnSZnO
C10399.95--0.001----0.005-杂质总合<0.03(除O、Ag外)T1、TU1
C10199.9--0.001----0.005-杂质总合<0.03(除O、Ag外)T2
C11099.99-------0.001-杂质总合<0.0050TU0

British standard chemical composition control table

Standard No.: bsg017-1981

牌号化学身分(质量分数)(%)不大于(注明余量及规模者除外)
CuPbFeZn其它元素杂质总和
CZ10189.0–91.00.050.1余量0.4
CZ10284.0–86.00.05
余量0.4
CZ10379.0–81.00.050.1余量0.4
CZ10479.0–81.00.05余量0.6
CZ10570.0–73.00.075余量As0.02–0.060.3
CZ10668.5–71.50.050.05余量0.3
CZ10764.0–67.00.10.1余量
0.4
CZ10862.0–650.30.2余量0.5(除Pb外)
CZ10959.0–62.00.1余量Sb0.02(如需要)0.3(除Pb外)
CZ11076.0–78.00.040.06余量Al1.80–2.300.3
As0.02–0.05
CZ11170.0–73.00.0750.06余量As0.02–0.060.3
Sn1.0–1.5
CZ11261.0–63.5余量Sn1.0–1.40.75
CZ11357.5–60.5余量Sn0.6–1.250.75
CZ11456.5–58.50.5–1.50.3–1.0余量Sn0.2–0.8、Al1.5、Mn0.5–2.00.5
(不包括Al)
CZ11556.5–58.50.5–1.50.3–1.0余量Sn0.2–0.8、Al0.1、Mn0.5–2.00.5
CZ11664.0–68.00.25–1.2余量Al4.0–5.0、0.5
Mn0.3–2.0
CZ11863.0–66.00.75–1.5余量0.3
CZ11961.0–64.01.0–2.5余量0.3
CZ12058.0–60.01.5–2.5余量0.3
CZ121Pb356.5–58.52.5–3.50.3余量0.7
CZ121Pb456.8–58.53.5–4.50.3余量0.7
CZ12256.5–58.51.5–2.50.3余量0.7
CZ12359.0–62.00.3–0.8余量0.3
CZ12460.0–63.02.5–3.70.3余量0.5(除Fe外)
CZ12595.0–98.00.020.05余量0.25
CZ12669.0–71.00.070.06余量As0.02–0.060.3
CZ12858.5–61.01.5–2.50.2余量0.5
CZ12958.5–61.00.8–1.50.2余量0.5
CZ13055.5–57.52.5–3.5余量Al0.50.7(不包括Al)
CZ13161.0–63.01.5–2.50.2余量0.5
CZ13260.0–63.01.7–2.80.235.0–37.0Sn0.2、As0.08–0.150.5
CZ13359.0–620.20.1余量Sn0.5–1.00.4
CZ13459.0–62.01.3–2.20.1余量Sn0.5–1.00.2
CZ13557.0–60.00.80.5余量Sn0.3、Al1.0–2.00.5(不包括Sn、Pb、Fe、Ni)
Ni0.2、Mn1.5–3.5
Si0.3–1.3
CZ13656.0–59.03余量Mn0.5–1.50.7(不包括Pb)
CZ13758.5–1.00.3–0.80.2余量0.5

European standard (en12164) chemical composition

成份牌号Cu铜Al铝Fe铁Ni镍Pb铅Sn锡Zn锌其他密度
(g/㎝3)
CuZn36Pb3 (CW603N)60-62<0.05<0.3<0.32.5-3.5<0.2其余0.28.5
CuZn38Pb4 (CW609N)57-59<0.05<0.3<0.33.5-4.2<0.3其余0.28.4
CuZn39Pb3 (CW614N)57-59<0.05<0.3<0.32.5-3.5<0.3其余0.28.4
CuZn40Pb2 (CW617N)57-59<0.05<0.3<0.31.6-2.5<0.3其余0.28.4
CuZn37Pb2 (CW606N)61-62<0.05<0.2<0.31.6-2.5<0.2其余0.28.4
CuZn38Pb2 (CW608N)60-61<0.05<0.2<0.31.6-2.5<0.2其余0.28.4
CuZn39Pb2 (CW612N)59-60<0.05<0.3<0.31.6-2.5<0.3其余0.28.4
CuZn35Pb1 (CW600N)62.5-64<0.05<0.1<0.30.9-1.6<0.1其余<0.18.5
CuZn35Pb2 (CW601N)62-63.5<0.05<0.1<0.31.6-2.5<0.1其余<0.18.5
CuZn38Pb1 (CW607N)60-61<0.05<0.2<0.30.8-1.8<0.2其余<0.28.4
CuZn39Pb0.5(CW610N)59-60.5<0.05<0.2<0.30.2-0.8<0.2其余<0.28.4
CuZn39Pb1 (CW611N)59-60<0.05<0.2<0.30.8-1.6<0.2其余<0.28.4
CuZn36Pb2As(CW602N)61-63<0.05<0.1<0.31.7-2.8<0.1其余<0.28.4

         Note: cuzn36pb2as (cw602n) as arsenic content: 0.02-0.05; Mn content < 0.1.

Analysis of common defects of copper alloy tube bar profiles

    1. Overheating and over burning:

definition:

    In the process of heating or processing, due to the high temperature and long time, the structure and grain size of the island are called overheating. In case of severe overheating, the melting point between grains is never low, and the phenomenon of component melting or grain boundary weakening is called overburning.

Causes:

a. The heating temperature is high, the heating time is long or the heating time is long;

b. The end temperature of hot extrusion is too high or the residence time in high temperature region is long;

c. There are many low melting point components or impurities in the alloy.

2. Cracks or cracks:

definition:

    Continuous or intermittent irregular cracks appear on the surface of tube bar profile, slight crack is called crack, and severe crack is called crack.

Causes:

a. There are cracks, inclusions, shrinkage cavity, porosity, cold shut or other harmful impurities or crystal structure and chemical composition in the ingot;

b. Large stress exists in the ingot or the improper processing technology produces large stress;

c. The extrusion speed is too fast and the processing rate is too high;

d. Improper heat treatment process, processing or heat treatment in the brittle temperature region of the material.

3. Tail retraction:

definition:

    Shrinkage tail is a special defect of extruded product tail. At the end of extrusion, due to metal turbulence, oxide scale, lubricant and other dirt often flow into the ingot surface, resulting in metal delamination.

Causes:

a. The metal flow in the extrusion tail is disordered;

b. There are defects on the surface and sub surface of ingot, and pollutants such as lubricant in extrusion cylinder.

4. Bubbling

definition:

    After extrusion, drawing and return, the surface of the product is bulged along the processing direction. After dissection, it becomes a cavity. This kind of bulging is called bubbling. The bubbles are mostly strip-shaped with smooth surface and metallic luster inside. Some associated oxides or other inclusions are found.

Causes:

a. After extrusion, drawing and cold rolling, delamination is formed along the processing direction;

b. Excessive lubricant in extrusion barrel;

c. The shrinkage tail of extruded products is not cut off completely, and the delamination is formed after further stretching.

5. Dezincification

    definition:

    After annealing or acid pickling, the surface of zinc containing copper alloy tube and rod appears gray or reddish spots, which is called dezincification. The above spots appeared slightly and the microstructure changed after serious dezincification.

    Causes:

a. If the annealing temperature is too high, the flame will spray directly on the surface of the products, which will melt, volatilize or oxidize the zinc in the mark;

b. The extrusion temperature is too high;

c. During acid pickling, the concentration of acid solution is too high and the pickling time is too long, which leads to surface dezincification;

d. Under the action of environmental medium, chemical or electrochemical reaction occurs to form dezincification.

    6. Pockmarked noodles (commonly known as pitted spots and trachoma)

    definition:

    The surface of pipe rod type wire rod appears tiny point like depression, and the uneven rough surface is called pockmarked surface. Pockmarks are distributed locally, periodically or in patches. Some of them are called pockmarks, and the serious ones are called pockmarks.

    Causes:

a. High annealing temperature and long annealing time lead to coarse grains and serious dezincification;

b. Over pickling;

c. The machining rate is too small and the surface is not smooth;

d. The surface of processing equipment or tool is not smooth, and foreign matters are stuck and formed after contacting with materials.

    7. Ring mark on the surface

    definition:

    The surface or inner wall of pipe rod type wire rod has periodic circular bulge, which is called as the surface ring mark.

    The ring marks on the surface are produced in the processes of stretching, peeling and straightening. The ring marks are generally smooth, and the edges and corners of some convex edges are found. During the straightening process, a special ring bulge along 450 direction appears.

   Causes:

    a. The reason of drawing ring is that annealing temperature is not uniform, process and lubrication are poor, and pickling is not complete;

    b. The reason of peeling ring is that the design of peeling die is unreasonable and the drawing speed is not suitable; or the edge of peeling die is not sharp and the chip removal resistance is high;

    c. The cause of straightening ring is improper adjustment of roller angle or excessive pressure.

    Grades and uses of commonly used copper alloys

    There are 6 kinds of common brass

    1. H96, used for condenser tube, radiator, radiator and conductive parts.

    H80, used for thin-walled pipe, bellows, etc.

    H70, used for mechanical and electrical parts, etc.

    H68, used for complex cold stamping parts, deep drawing parts, radiator shell, etc.

    5. H65, used for hardware, small spring, screw and machine parts, etc.

    6. H62, used for rivets, pins, conduits, nuts, etc.

   There are 3 common brands of lead brass

    1. Hpb63-2, used for mechanical parts of general strength.

    2. Hpb61-1, used for high strength structural parts.

    3. HPb59-1, used for hot stamping and cutting parts, such as pins, screws, etc.

    There are 2 common brands of manganese brass

    Hmn58-2 and hmn57-3-1 are mainly used for parts used in corrosion conditions and weak current industry.

    There are 3 common brands of tin brass

    Hsn90-1, used for automobile, tractor elastic sleeve and other anti-corrosion friction reducing parts.

    High temperature corrosion resistant tubes, such as HSN2, hsn70, etc.

    3. HSn62-1, which is used for parts in contact with sea water and gasoline.

    There are 2 common brands of iron brass

    1. Hfe59-1-1, used for parts working under friction and corrosion, such as gasket, bushing, etc.

    2. Hfe58-1-1, used for hot pressing and cutting of high strength corrosion resistant parts.

    Nickel brass

    Hni65-5, used for pressure gauge tube, condensing tube and paper net, etc.

    There are 5 common brands of tin bronze

    1. Qsn4-3, corrosion and wear-resistant parts, diamagnetic components and springs, etc.

    Qsn4-4-2.5, parts bearing friction, such as shaft sleeve, bearing, disc, etc.

    Qsn6.5-0.1, spring contact plate, wear-resistant and antimagnetic parts in precision instruments.

    4. Qsn6.5-0.4, used for paper-making copper mesh, spring, wear-resistant parts, etc.

    5. Qsn7-0.2, used for the workpiece bearing friction, such as bearing worm gear and spring.

    There are 5 common brands of aluminum bronze

    1. Qai5, used for corrosion resistant elastic components.

    2. Qai9-2, pipe fittings working in steam below 250 ℃.

    Qai9-4, used for bearings, gears, valve seats, ship parts and electrical components.

    Qai7, used for gear, friction wheel, worm gear transmission mechanism, etc.

    Qai10-3-1.5, used for wear-resistant parts under high temperature, such as bearing, gear, flywheel, etc.

    There are 2 common brands of beryllium bronze

    Qbe1.7, used for important spring, sensitive element of precision instrument, etc.

 2. QBe2, used for important elastic components, bearings under high speed and high temperature working conditions.

    There are 2 common brands of silicon bronze

1. QSi1-3, used for friction parts working below 300 ℃, such as inlet and exhaust valve guide sleeve.

2. QSi3-1, used for spring, worm gear, worm gear and corrosion resistant parts.

Manganese bronze

    Qmn5 is commonly used to manufacture steam engine parts, various pipe joints of worm gear, steam valves and other high-temperature corrosion-resistant parts.






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